Simple answer : If you want to shift 6 em to the left you do something like
\hspace*{-6em}
\begin{tabular}{ m{5em} m{14em} m{17em} m{4em} }
\hline
\textbf{Year} & \textbf{Degree/Certificate} & \textbf{Institute} & \textbf{CGPA}
\end{tabular}
Simple answer : If you want to shift 6 em to the left you do something like
\hspace*{-6em}
\begin{tabular}{ m{5em} m{14em} m{17em} m{4em} }
\hline
\textbf{Year} & \textbf{Degree/Certificate} & \textbf{Institute} & \textbf{CGPA}
\end{tabular}